Why does the Tafel slope in Figure 9.12 deviate from linearity?... | Filo
Why does the Tafel slope in Figure 9.12 deviate from linearity?... | Filo
5.5K views7 months ago
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SOLVED: Because of the Frumkin effect, Tafel plots are not linear and have the following varying slopes in the cathodic region: f[-α (α-z)((∂ϕ2)/(∂η))] (a) Derive this equation. (b) Asada, Delahay, and Sundaram [J. Am. Chem. Soc., 83, 3396 (1961)] suggested that a plot of ln[i (z F ϕ2 / R T)] against ϕ2-η(a "corrected Tafel plot") is linear and has a slope of αF / R T. Show, by suitable manipulation of the equations, that this is so. | Numerade
SOLVED: Because of the Frumkin effect, Tafel plots are not linear an…
Apr 9, 2024
numerade.com
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